Enhanced removal of Chloramphenicol drug by low cost superabsorbent hydrogel nanocomposite: Optimization, isotherm, and thermodynamic modelling non-linear

Document Type : Research Paper

Authors

1 Department of Chemistry, College of Science, University of Babylon, Hilla, Iraq

2 Department of Chemistry, College of Sciences for Girls, University of Babylon, Hilla, Iraq

10.22124/cjes.2024.7559

Abstract

In this work, an eco-friendly, stable, simple, new super adsorbent adsorption properties based on biopolymer sodium alginate was successfully deliberated by a combination of a simple crosslinking method. We prepared two hydrogel including (SA-g-P(Ac-co-AM) hydrogel and the second hydrogel after loading CNT/ZnO onto   hydrogel.  These new hydrogel surfaces were prepared from two monomers (acryl acid and acrylamide) to remove Chloramphenicol CHZ drug. The physical characterizations of new super adsorbent hydrogel nanocomposite were evaluated by XRD, FTIR, TGA, EDX and TEM. The practical experiments involved calculation of the best wavelength and study of best condition of adsorption factors such as effect of equilibrium time, weight of hydrogel nanocomposite, temperature solution, pH solution, and adsorbent regeneration experiments (Desorption). The removal percentage of CHZ drug   increased from 55.45 to 89.8%, and adsorption capacity was changed from 65.5 to 110 mg g-1 on to hydrogel nanocomposite. The isotherm Freundlich and isotherm Langmuir were too introduced. All data followed the model Freundlich isotherm in the presence of CHZ drug. The change enthalpy (∆H) value was positive indicating the adsorption method endo-thermic presses and spontaneous of change Gibes free energy (∆G) negative value, as well as positive value of   change entropy (∆S).

Keywords

References

Abdalghaffar, OAHM & Tawfik, AS 2020, Simultaneous adsorption of dye and toxic metal ions using an interfacially polymerized silica/polyamide nanocomposite: Kinetic and thermodynamic studies. Journal of Molecular Liquids, 314: 113640.
Al Bayati, RA 2020, Adsorption-desorption isotherm of one of antidiabetic drug from aqueous solutions on some pharmaceutical adsorbents. European Journal of Scientific Research, 40: 580-588.
Al Niaeem, HS & Hanoosh, W 2022, Preparation of semi IPNs-hydrogel composite for removing Congo Red and Bismarck Brown Y from wastewater: Kinetic and thermodynamic study. Egyptian Journal of Chemistry, 56: 19 - 34.
Aljeboree, AM & Alkaim, AF 2019, Comparative removal of three textile dyes from aqueous solutions by adsorption: As a model (corn-cob source waste) of plants role in environmental enhancement. Plant Archives, 19: 1613-1620.
Aljeboree, AM & Alkaim, AF 2019, Role of plant wastes as an ecofriendly for pollutants (Crystal Violet dye) removal from aqueous solutions. Plant Archives, 19: 902-905.
Aljeboree, AM & Alshirifi, AN 2018, Spectrophotometric determination of phenylephrine hydrochloride drug in the existence of 4-aminoantipyrine: Statistical study. International Journal of Pharmaceutical Research, 10: 576-584.
Aljeboree, AM & Alshirifi, AN 2019, Oxidative coupling of Amoxicillin using 4-Aminoantipyrine: Stability and higher sensitivity. In: Journal of Physics: Conference Series.
Aljeboree, AM, Al Baitai, AY, Abdalhadi, SM & Alkaim, AF 2021, Investigation study of removing methyl violet dye from aqueous solutions using corn-cob as a source of activated carbon. Egyptian Journal of Chemistry, 64: 2873-2878.
Aljeboree, AM, Hussein, FH & Alkaim AF 2019, Removal of textile dye (methylene blue MB) from aqueous solution by activated carbon as a model (corn-cob source waste of plant): As a model of environmental enhancement. Plant Archives, 19: 906-909.
Alkaim, AF & Aljeobree, AM 2020, White marble as an alternative surface for removal of toxic dyes (Methylene blue) from Aqueous solutions. International Journal of Advanced Science and Technology, 29: 5470-5479.
Alshamri, AM, Alqaragully, MB & Alkaim, AF 2021, Removal of toxic textile dyes from aqueous solution through adsorption onto coconut husk waste: Thermodynamic and isotherm studies. Caspian Journal of Environmental Sciences, 19: 513~522
Bashir, WA & Hamoudi, TA 2013, Spectrophotometric Determination of chloramphenicol in pharmaceutical preparations. Journal of Education and Science, 27: 19-35.
Chayid, MA & Ahmed, MJ 2015, Amoxicillin adsorption on microwave prepared activated carbon from Arundo donax Linn: Isotherms, kinetics, and thermodynamics studies. Journal of Environmental Chemical Engineering, 3: 1592-1601.
del Mar Orta, M, Martn, J, Medina Carrasco, S, Santos, JL, Aparicio, I & Alonso, E 2019, Adsorption of propranolol onto montmorillonite: Kinetic, isotherm and pH studies. Applied Clay Science, 173: 107-114.
Esmaeili, H, Foroutan, R, Jafari, D & Rezaei, MA 2021, Effect of interfering ions on phosphate removal from aqueous media using magnesium oxide@ferric molybdate nanocomposite. Korean Journal of Chemical Engineering ,37: 804-814.
Gamoudi, S & Srasra, E 2019, Adsorption of organic dyes by HDPy+-modified clay: effect of molecular structure on the adsorption. Journal of Molecular Structure.
León, G, Saura, F, Hidalgo, AM & Miguel, B 2021, Activated olive stones as a low-cost and environmentally friendly adsorbent for removing cephalosporin c from aqueous solutions. International Journal of Environmental Research and Public Health, 18: 4489.
Luo, Q, Ren, T, Lei, Z, Huang, Y, Huang, Y, Xu, D, Wan, C, Guo, X & Yiqiang, W 2022, Non-toxic chitosan-based hydrogel with strong adsorption and sensitive detection abilities for tetracycline. Chemical Engineering Journal, 427: 131738.
Luo, S 2020, ZnO nanorod arrays assembled on activated carbon fibres for photocatalytic degradation: Characteristics and synergistic effects. Chemosphere, 261: 127731.
Mahmoud, KM 2007, Determination of Chloramphenicol from pure and pharmaceutical preparations using FIAS pectrophotometric methods. National Journal of Chemistry, 28: 634-641.
Mohammed A Jawad, AJK & Radia, ND 2021, Role of sodium alginate-g-poly (acrylic acid-fumaric acid) hydrogel for removal of pharmaceutical paracetamol from aqueous solutions by Adsorption International Journal of Pharmaceutical Quality Assurance, 12: 202-205.
Pashaei Fakhri, S, Peighambardoust, SJ, Foroutan , R, Arsalani, N & Ramavandi, R 2021, Crystal violet dye sorption over acrylamide/graphene oxide bonded sodium alginate nanocomposite hydrogel. Chemosphere, 270: 129419.
Powers, HJ 2003, Riboflavin (vitamin B2) and health. The American Journal of Clinical Nutrition, 77: 1352-1360.
Tassew Alemayehu, AS 2013, Determination of chloramphenicol in pharmaceutical samples at electrochemically pretreated glassy carbon electrode. American Scientific Research Journal for Engineering, Technology, and Sciences (ASRJETS), 6: 1-11.
Yasin, AS, Kim, DH & Lee, K 2021, One-pot synthesis of activated carbon decorated with ZnO nanoparticles for capacitive deionization application. Journal of Alloys and Compounds, 870: p. 159422.
Zheng, MC, Chen, M, Zhu, Y, Zhang, L & Zheng, B 2020, pH-responsive poly(gellan gum-co-acrylamide-co-acrylic acid) hydrogel: Synthesis, and its application for organic dye removal. International Journal of Biological Macromolecules, 153: 573-582.
Zhou, M, et al. 2013, Uniform hamburger-like mesoporous carbon-incorporated ZnO nanoarchitectures: One-pot solvothermal synthesis, high adsorption and visible-light photocatalytic decolorization of dyes. Applied Catalysis B: Environmental, 138-139: 1-8.
Caspian Journal of Environmental Sciences

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Available Online from 14 February 2024

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