Preparation and characterization of cadmium (ll), zinc (ll) and copper (ll) ion complexes using new triazene ligands and study of their biological activity

Document Type : Research Paper

Authors

University of Babylon, Chemistry Department, College of Science for Women, Iraq.

10.22124/cjes.2023.6764

Abstract

The synthesis of the novel ligand was disclosed in this study this ligand was synthesized from react between 4-amino anti pyrene with 6-amino pencillanic acid by triazene reaction. The ligand was identified by FT-IR, UV-Visible ,HNMR, Mass spectroscopy reacting the ligand with salts of transition metals Cu, Zn, Cd (II) complexes and gave octahedral, hybridization sp3d2 complexes with a molar ratio (1:2) M:L Magnetic Para-Di complexes were produced using amoral ratio of metal chloride to ligand spectroscopic data used to establish the identity of ligand of their corresponding complexes by FT-IR, UV-VIS, Atomic absorption,  magnetic susceptibility and conductivity. The ligand and its complex exhibited biological activity. It gave good results in inhibiting gram positive Streptococcus bacteria.

Keywords