Introducing a novel chemical method of treatment for dye removal: Removal of Maxillon Blue and Direct Yellow from aqueous solution

Document Type : Research Paper

Authors

1 Department of Chemistry, College of Sciences for Girls, University of Babylon, Hilla, Iraq

2 College of Dentistry, Alkafeel University, Najaf, Iraq

3 Department of Chemistry, College of Education, University of Al-Qadisiyah, Iraq

Abstract

Many industrial and chemical dyes are used in many industrial processes, a variety of different uses. Among the most important of these industries, fabric dyeing, many textiles, papermaking, printing and leather processing, and most food products, and other industries, use industrial dyes, and the waste emitted from these dyes in most industries in which most of the polluted waste resulting from these remnants is produced factories. Therefore, the best methods were adopted to treat and dispose of these dyes in order to preserve the aquatic environment .In the current study, the adsorption characteristics of two dyes, Maxillon blue (GRL) and Direct yellow (DY12), from an aqueous solution were evaluated. The effect of several factors, for example, initial concentration, pH solution, temperature, adsorbent mass, and equilibrium time, have been study. The adsorption capacity and percentage of color removed upraised by elevating contact time and surface area, also elevated by the upraised temperature solution for GRL and DY12, and also the adsorption efficiency decreased by the raised adsorbent dosage. The optimum equilibrium for contact time to be completed is found to be (60 min) 1 hour. It is essentially due to the saturation of the active site that does not let further adsorption to take place. The adsorption was proved through utilizing (FT-IR) and (F.E-SEM) analysis. In addition, TGA appears that the NTADCIP/P (AA-co-AM) composite is stable in high temperatures. GRL adsorbent surfaces best adsorption found to be at pH = 10. In fact, adsorption was found to increase through the rise in solution pH.  However DY12 maximum dye adsorption was found to be at pH = 3.  The applicability of isotherms adsorption to study the adsorption behavior has to been analyzed via isotherm models Freundlech and Langmuir were utilized to illustrate the experimental model and isotherm's constants. It was found the Freundlech model gives the best fits when compare with Langmuer isotherm for two dyes.

Keywords

References

Abdulsahib, WK, Ganduh, SH, Radia, ND & Jasim, LS 2020, New approach for sulfadiazine toxicity management using carboxymethyl cellulose grafted acrylamide hydrogel. International Journal of Drug Delivery Technology, 10:  259-264.
Al-Hayder, L & Al-Hussainawy, M 2016, A kinetics study of E. coli and S. aureus adsorption on cross linked hydro gels. International Journal of ChemTech Research,  9: 337-344.
Al-Hayder, LJ  & AL-Juboor MJ 2015, Removal study of imidacloprid from aqueous solution by adsorption onto polyacrylamide cross-linked. Journal of Chemical and Pharmaceutical Research,  7: 1138-1144.
Aljeboree, AM & Alshirifi, AN 2018, Colorimetric determination of phenylephrine hydrochloride drug Using 4-Aminoantipyrine: Stability and higher sensitivity. Journal of Pharmaceutical Sciences and Research,  10(7): 1774-1779.
Aljeboree, AM 2016, Adsorption of crystal violet dye by Fugas Sawdust from aqueous solution. International Journal of ChemTech Research,  9: 412-423.
Aljeboree, AM, Hussein, FH &  Alkaim, AF 2019, Removal of textile dye (methylene blue mb) from aqueous solution by activated carbon as a model (corn-cob source waste of plant): As a model of environmental enhancement. Plant Archives,  19: 906-909.
Alkaim, AF & Alqaraguly, MB 2013, Adsorption of basic yellow dye from aqueous solutions by activated carbon derived from waste apricot stones (ASAC): equilibrium, and thermodynamic aspects. international journal of chemical sciences,  11: 797-814.
Alkaim, AF, Alrobayi, EM, Algubili, AM & Aljeboree AM 2017, Synthesis, characterization, and photocatalytic activity of sonochemical/hydration–dehydration prepared ZnO rod-like architecture nano/microstructures assisted by a biotemplate. Environmental Technology,  38: 2119-2129.
Alkherraz, AM, Ali, AK, &Elsherif, KM 2020, Equilibrium and thermodynamic studies of Pb (II), Zn (II), Cu (II) and Cd (II) adsorption onto mesembryanthemum activated carbon. Journal of Medicinal and Chemical Sciences 3: 1-13.
Alrobayi, EM, Algubili, AM, Aljeboree, AM, Alkaim, AF &  Hussein, FH 2017, Investigation of photocatalytic removal and photonic efficiency of maxilon blue dye GRL in the presence of TiO2 nanoparticles. Particulate Science and Technology,  35: 14-20.
Aqel, A, Abou El-Nour, KM, Ammar, RA & Al-Warthan, A 2012, Carbon nanotubes, science and technology part (I) structure, synthesis and characterisation. Arabian Journal of Chemistry,  5: 1-23.
Arya, V  & Philip, L 2016, Adsorption of pharmaceuticals in water using Fe3O4 coated polymer clay composite. Microporous and Mesoporous Materials,  232: 273-280.
Atyaa, AI, Radhy, ND & Jasim, LS 2019, Synthesis and characterization of Graphene Oxide/hydrogel composites and their applications to adsorptive removal Congo Red from aqueous solution. In Journal of Physics: Conference Series (1234:012095). IOP Publishing.
Banimahd Keivani, M 2018, Removal of brilliant blue pollution from the environment using nano polyaniline hazelnut skin composite and evaluation of effective parameters. Caspian Journal of Environmental Sciences,  16: 249-258.
Bozorgpanah Kharat, Z, Mohammadi Galangash, M, Ghavidast, A & Shirzad-Siboni, M 2018, Removal of reactive black 5 dye from aqueous solutions by Fe3O4@ SiO2-APTES nanoparticles. Caspian Journal of Environmental Sciences,  16: 287-301.
Chaturvedi, S & Dave, PN 2019, Water purification using nanotechnology an emerging opportunities. Chemical Methodologies, 3:115.
Danner, MC, Robertson, A, Behrends, V & Reiss J 2019, Antibiotic pollution in surface fresh waters: occurrence and effects. Science of the Total Environment,  664: 793-804.
Del Águila-Carrasco, AJ, Lara, F, Bernal-Molina, P, Riquelme-Nicolás, R, Marín-Franch, I, Esteve-Taboada, JJ, Montés-Micó, R, Kruger, PB &  López-Gil, N 2019, Effect of phenylephrine on static and dynamic accommodation. Journal of Optometry,  12: 30-37.
Hatami, A 2021, Preparation, description and evaluation of the lethality acid loaded liposomal nanoparticles against in vitro colon and liver cancer. Journal of Chemical Reviews, 3: 121.
Ho, YJ, Eichendorff, J & Schwarting, RK 2002, Individual response profiles of male Wistar rats in animal models for anxiety and depression. Behavioural Brain Research,  136: 1-12.
Hosseinpour, J, Bravo, L & Samimi-Abianeh, O 2018, Computational study of unsteady cavitating flows and erosion in a fuel nozzle. In: ASME 2018 Internal Combustion Engine Division Fall Technical Conference, American Society of Mechanical Engineers Digital Collection.
Hunger, K 2007, Industrial dyes: chemistry, properties, applications. John Wiley & Sons.
Ji, L, Liu, F, Xu, Z, Zheng, S & Zhu, D 2010, Adsorption of pharmaceutical antibiotics on template-synthesized ordered micro-and mesoporous carbons. Environmental Science & Technology,  44:  3116-3122.
Karim, AN & Jasim, LS 2019, Synthesis and characterization of poly (CH/AA-co-AM) composite: Adsorption and thermodynamic studies of benzocaine on from aqueous solutions. International Journal of Drug Delivery Technology,  9: 558-562.
Kumar, PS, Ramalingam, S, Senthamarai, C, Niranjanaa, M, Vijayalakshmi, P & Sivanesan, S 2010, Adsorption of dye from aqueous solution by cashew nut shell: Studies on equilibrium isotherm, kinetics and thermodynamics of interactions. Desalination,  261: 52-60.
Langmuir, I 1918, The adsorption of gases on plane surfaces of glass, mica and platinum. Journal of the American Chemical Society,  40: 1361-1403.
Mahde, BW, Radia, ND, Jasim, LS & Jamel, HO 2018, Synthesis and characterization of polyacrylamide hydrogel for the controlled release of aspirin. Journal of Pharmaceutical Sciences and Research,  10: 2850-2854.
Quesada, HB, Baptista, ATA, Cusioli, LF, Seibert, D, de Oliveira Bezerra, C & Bergamasco, R 2019, Surface water pollution by pharmaceuticals and an alternative of removal by low-cost adsorbents: A review. Chemosphere,  222: 766-780.
Radhy, ND & Jasim, LS 2019, Synthesis of Graphene Oxide/hydrogel composites and their ability for efficient adsorption of Crystal Violet. Journal of Pharmaceutical Sciences and Research,  11: 456-463.
Sharma, G & Sharma, S 2021, Synthetic impatienol analogues as potential cyclooxygenase-2 inhibitors: a preliminary study. Journal of Applied Organometallic Chemistry, 1: 66.
Shikha, R & Jha, AK 2019, Relative phytotoxicity of stem and root aqueous extracts of Parthenium hysterophorus L. on Cicer aeritinum. Journal of Research in Weed Science, 2:  372-380.
Xiong, R, Zhang, X, Tian, D, Zhou, Z & Lu, C 2012, Comparing microcrystalline with spherical nanocrystalline cellulose from waste cotton fabrics. Cellulose,  19: 1189-1198.
Yang, R, Li, D, Li, A & Yang, H 2018, Adsorption properties and mechanisms of palygorskite for removal of various ionic dyes from water. Applied Clay Science,  151: 20-28.
 
Caspian Journal of Environmental Sciences
Volume 19, Issue 4
October 2021
Pages 673-684

Files

Share

How to cite

Statistics